Document Type : Research Paper

Authors

1 Department of Environment, Ardabil Branch, Islamic Azad University, Ardabil, Iran.

2 Department of Agriculture, Ardabil Branch, Islamic Azad University, Ardabil, Iran.

3 Department of Environment, Shahrood Branch, Islamic Azad University, Shahrood, Iran.

4 Department of Water Engineering, Shiraz Branch, Islamic Azad University, Shiraz, Iran.

10.22126/arww.2025.10788.1337

Abstract

Different methods and indicators are employed to determine water quality. In this study, to assess the quality of the international Aras River, 16 parameters were analyzed at 19 stations with seasonal data collected over two years (2020 and 2021), and multivariate statistical analysis methods, including cluster analysis and factor analysis, were utilized. The cluster analysis results categorized the studied stations into four clusters based on quality. The primary parameters influencing the grouping of water quality at the stations were BOD, COD, and T. Coli in the first cluster; T. Coli and NO3 in the second cluster; TDS, EC, and Turbidity in the third cluster; and BOD, COD, TDS, EC, and Turb. in the fourth cluster, respectively. The principal component analysis and factor analysis results indicated that the first two components explained 86% of the total variance. In the first component, with an eigenvalue of 5.94, the most influential parameters in the qualitative classification of the stations included pH, DO, EC, T. Coli, NO3, and Hg. In the second component, with an eigenvalue of 2.72, the parameters BOD, COD, Turb., and As played the most significant role in creating quality differences among the stations. Therefore, based on the obtained results, it was revealed that the reason for qualitative changes at different stations is due to the entry of human pollutants from various urban, industrial, mining, and agricultural sources as well as erosion in the river basin. Therefore, given the high precision of the analytical methods used in the evaluation of the qualitative aspects of the studied river’s water, it can be acknowledged that multivariable methods such as cluster analysis and factor analysis, can confidently determine the water quality of rivers and significant parameters affecting their quality and identify pollutants in the management of river water quality.

Keywords

Babolhakami, A. and Gholami Sefidkouhi, M.A. (2019) ‘Analyze of Talar River water quality using multivariate techniques’, Journal of Watershed Management Research, 9(18), pp. 250-259. doi: https://doi.org/10.29252/jwmr.9.18.250
Aghayari Samian, R. et al. (2023) 'The effect of climate change on surface runoff fluctuations in the Aras River basin', Hydrogeomorphology, 9(33), pp. 85-61. doi: https://doi.org/10.22034/hyd.2022.51870.1643
Abbasi, B., Maleki, R. Pirkharati H. (2017) ‘Study effects of mining and gold extraction on amount of water contamination to As and Hg in Zarshoran area of Takab’, Journal of Environmental Geology (in Persian) (2017), pp. 49:39-48. Available at: https://sanad.iau.ir/fa/Article/931362?FullText=FullText (Accessed date: 17 January 2024).
Aydin, H. et al. (2020) ‘Assessment of water quality of streams in northeast Turkey by water quality index and multiple statistical methods’, Environmental Forensics, 22 (1–2), pp. 270–287. doi: https://doi.org/10.1080/15275922.2020.1836074
Belkhiri, L. and Narany, T.S. (2015) ‘Using multivariate statistical analysis, geostatistical techniques and structural equation modeling to identify spatial variability of groundwater quality’, Water Resource Management, 29, pp. 2073–2089. doi: https://doi.org/10.1007/s11269-015-0929-7
Behbahaninia, A. and Farahani, M. (2016) ‘Investigation of natural sources contamination with Arsenic in the Suburbs of Hashtrood city', East Azerbayjan Provincem, Journal of Environmental Science and Technology, 2, pp. 469-475. Available at: https://sanad.iau.ir/en/Article/839954 (Accessed date: 15 February 2024).
Cheraghi, Z. et al. (2019) ‘Evaluation and statistical analysis of groundwater quality parameters and index for drinking in khorramabad region’, Water Engineering, 11(39), pp. 1-14. Available at: https://sid.ir/paper/169398/en (Accessed date: 18 January 2024).
De Andrade Costa, D. et al. (2020) ‘Water quality assessment based on multivariate statistics and water quality index of a strategic river in the Brazilian Atlantic Forest', Scientific Reports, 10, p. 22038. doi: https://doi.org/10.1038/s41598-020-78563-0
Ebadati, N. (2017) ‘Statistical analysis of Dez River water quality, Southwest of Iran’, Anthropogenic Pollution', 1 (1), pp. 46-60. doi: https://doi.org/10.22034/apj.2017.1.1.4660
Fataei, E. and Shiralipoor, S. (2011) ‘Evaluation of surface water quality using cluster analysis: a case study’, World Journal of Fish and Marine Sciences, 3(5), pp. 366-370. doi: https://doi.org/10.5829/idosi.wjfms.2012.04.01.6193
Ghassemi Dehnavi, A. et al. (2016) ‘Qualitative and quantitative evaluation of surface water using statistical analysis in Azna River, Lorestan', Environment and Water Engineering, 2(4), pp. 306-321. Available at: https://www.jewe.ir/article_40977.html?lang=en (Accessed date: 20 January 2024).
Giao, N. T. (2022) 'Analysis of surface water quality using multivariate statistical approaches: A case study in Ca Mau Peninsula, Vietnam', Pollution, 8(2), pp. 463-477. doi: https://doi.org/10.22059/poll.2021.329252.1165
Govender, P. and Sivakumar, V. (2020) ‘Application of k-means and hierarchical clustering techniques for analysis of air pollution: A review (1980–2019)', Atmospheric Pollution Research, 11, pp. 40–56. doi: https://doi.org/10.1016/j.apr.2019.09.009
Hajigholizadeh, M. and Melesse, A.M. (2017) ‘Assortment and spatiotemporal analysis of surface water quality using cluster and discriminant analyses’, CATENA, 151, pp. 247-258. doi: https://doi.org/10.1016/j.catena.2016.12.018
Ildorom, A., Hassanzadeh, N. and Hedayatzadeh, F. (2022) ‘Evaluation of spatial and temporal variation of water quality parameters of Karkheh River and the suitability of its quality for irrigation purposes', Journal of Wetland Ecobiology, 13(50), pp. 33-54. Available at: https://sid.ir/paper/1059494/en (Accessed date: 24 January 2024).
Jalili, S. (2020) ‘Water quality assessment based on HFBI & BMWP index in Karoon River, Khuzestan Province, (Northwest of Persian Gulf)', Anthropogenic Pollution, 4(1), pp. 36-49. doi: https://doi.org/10.22034/AP.2020.1877482.1047
Jalilzadeh Yengejeh, R., Morshedi, J. and Yazdizadeh, R. (2014) ‘The study and zoning of dissolved oxygen (DO) and biochemical oxygen demand (BOD) of Dez River by GIS software', Journal of Applied Research in Water and Wastewater, 1(1), pp. 23-27. Available at: https://arww.razi.ac.ir/article_47.html (Accessed date: 26 January 2024).
Kazemi Noredinvand, B., Takdastan, A. and Jalilzadeh Yengejeh, R. (2015) ‘Removal of organic matter from drinking water by single and dual media filtration: a comparative pilot study', Desalination and Water Treatment, 57(44), pp. 20792–20799. doi: https://doi.org/10.1080/19443994.2015.1110718
Khoshnoodmotlagh, R. et al. (2020) ‘Transboundary basins need more attention: anthropogenic impacts on land cover changes in Aras River Basin, monitoring and prediction', Remote Sensing 12(20), pp. 3329-3335. doi: https://doi.org/10.3390/rs12203329
Ling, T. et al. (2017) ‘Application of multivariate statistical analysis in evaluation of surface river water quality of a Tropical River’, Journal of Chemistry', 2017, p. 5737452.
doi: https://doi.org/10.1155/2017/5737452
Lausch, A. and Herzog, F. (2002) ‘Applicability of landscape metrics for the monitoring of landscape change: issues of scale, resolution, and interpretability', Ecological Indicators, 2(1-2), pp. 3-15. https://doi.org/10.1016/S1470-160X(02)00053-5
Mackialeagha, M., Salarian, M.B. and Behbahaninia, A. (2022) ‘The use of multivariate statistical methods for the classification of groundwater quality: a case study of aqueducts in the east of Tehran, Iran', Anthropogenic Pollution, 6(2), pp. 1-9. doi: https://doi.org/10.22034/ap.2022.1965587.1134
Mohammadi, J. et al. (2023) ‘Investigation and determination of land use effects on surface water quality in semi-arid areas: Case study on Qarasu River in Iran', Anthropogenic Pollution, https://doi.org/10.57647/j.jap.2023.0702.19
Mohammadi Ghaleni, M. and Kardan Moghaddam, H. (2022) 'Introducing a new drinking water quality index for surface water resources using multivariate analysis (Case study: Sefidroud River)', Water and Soil, 36(4), pp. 439-458. doi: https://doi.org/10.22067/jsw.2022.77413.1177
Mostafavi, A. Teimori, A. (2018) ‘Investigating multiple human pressure types in the southern Caspian Sea Basin Rivers at different spatial scales toward Integrating Water Resource Management (IWRM) in Iran', Anthropogenic Pollution, 4(1), pp. 17-28. doi: https://oiccpress.com/ap/article/view/3402
Muangthong, S. and Shrestha S. (2015) ‘Assessment of surface water quality using multivariate statistical techniques: Aase study of the Nampong River and Songkhram River, Thailand', Environmental Monitoring Assessment, 187(9), p. 548. doi: https://doi.org/10.1007/s10661-015-4774-1
Muniz, D. H. F. and Oliveira-Filho, E.C. (2023) ‘Multivariate statistical analysis for water quality assessment: A review of research published between 2001 and 2020', Hydrology, 10(10), p. 196. https://doi.org/10.3390/hydrology10100196
Neissi, L. and Tishehzan, P. (2018) 'Dez River water quality assessment by using multivariate statistical methods', Irrigation and Water Engineering, 9(1), pp. 139-150. Available at: https://www.waterjournal.ir/article_81860.html?lang=en (Accessed date: 5 January 2024).
Nirmalakhandan N. (2002). Modeling tools for environmental engineers and scientists' Translated from the English by Fataei, E. et al. New York: CRC Press LLC, 313 pages.
Noshadi, M. and Ghafourian A. (2016) ‘Groundwater quality analysis using multivariate statistical techniques (case study: Fars province, Iran)', Environmental Monitoring Assessment, 188(7), p. 419. doi: https://doi.org/10.1007/s10661-016-5412-2
Poyraz, B. and Taspinar, F. (2014) 'Analysis, assessment and principal component analysis of heavy metals in drinking waters of Industrialized Region of Turkey', International Journal of Environmental Research, 8(4), pp. 1261-1270. doi: https://doi.org/10.22059/ijer.2014.818
Rafiei, B. et al. (2010) 'Distribution of heavy metals around the Dashkasan Au Mine', International Journal of Environmental Research, 4(4), pp. 647-654. doi: https://doi.org/10.22059/ijer.2010.250
Ravanbakhsh, M. et al. (2019) ‘Evaluation of temporal and spatial variations of water quality parameters in Zohreh River, Iran', Avicenna Journal Environmental Health Engineering, 6(2), pp. 75-82. doi: https://doi.org/10.34172/ajehe.2019.10
Rezaei, A. and Sayadi, M.H (2015) ‘Long-term evolution of the composition of surface water from the River Gharasoo, Iran: A case study using multivariate statistical techniques', Environmental Geochemistry and Health, 37(2), pp. 251-61. doi: https://doi.org/10.1007/s10653-014-9643-2
Safizadeh, E. et al. (2021) ‘Investigation of physicochemical properties of water in downstream areas of selected dams in Aras catchment and water quality assessment (Case study: Aras catchment in the border area of Iran and Armenia)', Anthropogenic Pollution, 5(1), pp. 41-48. doi: https://doi.org/10.22034/ap.2021.1912491.1082
Sadjadi, N., Davoodi, M. Jozi, S.A. (2019) ‘The quality assessment of Kan River & resources in terms of agricultural and drinking purposes', Anthropogenic Pollution, 3(1), pp. 46-53. doi: 10.22034/ap.2019.582368.1036
Saavedra, J. et al. (2013) ‘Principal component analysis as an exploration tool for kinetic modeling of food quality: a case study of a dried apple cluster snack', Journal of Food Engineering, 119, pp. 229-235. doi: https://doi.org/10.1016/j.jfoodeng.2013.05.036
Sayemuzzaman M. et al. (2018) ‘Multivariate statistical and trend analyses of surface water quality in the central Indian River Lagoon area', Florida', Environmental Earth Science, 77(4), pp. 1-13. doi: https://doi.org/10.1007/s12665-018-7266-0
Salahi, B., Saber, M. and Mofidi, A. (2022) 'Evaluation of evapotranspiration changes in the Aras basin using spatial high resolution MOD16 product', Iranian Journal of Geophysics, 16(2), pp. 119-137. doi: https://doi.org/10.30499/ijg.2022.317879.1382
Yağanoğlu E. et al. (2020) ‘Determination of spatial and temporal changes in surface water quality of Filyos River (Turkey) using principal component analysis and cluster analysis', Marine Science and Technology Bulletin, 9(2), pp. 207-214. https://doi.org/https://doi.org/10.33714/masteb.784959
Zamani-Ahmadmahmoodi, R. et al. (2019) 'Water quality assessment of the Beheshtabad River using Liou pollution index and principal component analysis', Water and Soil, 33(3), pp. 405-417. doi: https://doi.org/10.22067/jsw.v0i0.79102
Zhang B. et al. (2012) ‘Hydrochemical characteristics and water quality assessment of surface water and groundwater in Songnen plain, Northeast China', Water Research, 46(8), pp. 2737-2748. doi: https://doi.org/10.1016/j.watres.2012.02.033