Document Type : Research Paper

Authors

1 Department of Chemical and Petroleum Engineering, Sharif University of Technology,Tehran, Iran

2 Department of Applied Chemistry, Faculty of Chemistry, Kharazmi University,Tehran, Iran

3 Biotechnology Group, Chemical Engineering Department, Tarbiat Modares University, Tehran, Iran

Abstract

Wastewater reuse has been attracted a lot of attention in recent years especially in places with low water availability. The effluents that were considered to be discharged are now could be used as potential sources of reusable water. In this study, variables affecting the removal of ethylene glycol (EG) by adsorption on granular activated carbon (GAC) from the synthetic wastewater solutions were optimized by response surface methodology (RSM) using a central composite design. The investigated factors were temperature, EG concentration, contact time, activated carbon amount and granular size. Adsorption kinetic was also studied and an acceptable correlation between Langmuir model and experimental data was observed. As a result, a modified third degree equation was proposed and used to find the optimized condition. The maximum adsorption was achieved at 27.7 ºC with 0.8 g of 20-30 mesh activated carbons for an EG feed concentration of 135 mg/L at 210 minutes.

Keywords

Anderson J., Walking like dinosaurs: Water, reuse and urban jungle footprints, in: Water Recycling Australia, AWA 2nd National Conference, Brisbane, Australia, 2003.
Arulkumar M., Sathishkumar P., Palvannan T., Optimization of Orange G dye adsorption by activated carbon of Thespesia populnea pods using response surface methodology, Journal of Hazardous Materials 186 (2011) 827-834.
Bansal R.C., Goyal M., Activated carbon adsorption, CRC press, 2005.
Bernhard M., Eubeler J.P., Zok S., Knepper T.P., Aerobic biodegradation of polyethylene glycols of different molecular weights in wastewater and seawater, Water Research 42 (2008) 4791-4801
Cadar O., Paul M., Roman C., Miclean M., Majdik C., Biodegradation behaviour of poly (lactic acid) and (lactic acid-ethylene glycol-malonic or succinic acid) copolymers under controlled composting conditions in a laboratory test system, Polymer Degradation and Stability 97 (2012) 354-35.
Carnegie D., Ramsay J., Anaerobic ethylene glycol degradation by microorganisms in poplar and willow rhizospheres, Biodegradation 20 (2009) 551-558.
Dwyer D.F., Tiedje J.M., Degradation of ethylene glycol and polyethylene glycols by methanogenic consortia, Appl. Environmental Microbiology 46 (1983) 185-190.
Dye R.F., Ethylene glycols technology, Korean Journal of Chemical Engineering18 (2001) 571-579.
Devlin J., Schwartz M., Ethylene glycol, Encyclopedia of toxicology, third ed. Elsevier Inc, (2014) 525-527.
Eisenreich S.J., Looney B.B., Thornton J.D., Airborne organic contaminants in the Great Lakes ecosystem, Environmental Science & Technology 15 (1981) 30-38.
Elreedy A., Tawfik A., Effect of Hydraulic Retention Time on Hydrogen Production from the Dark Fermentation of Petrochemical Effluents Contaminated with Ethylene Glycol, Energy Procedia 74 (2015) 1071-1078.
Esfandiar N., Nasernejad B., Ebadi T., Removal of Mn (II) from groundwater by sugarcane bagasse and activated carbon (a comparative study): Application of response surface methodology (RSM), Journal of Industrial and Engineering Chemistry 20 (2014) 3726-3736.
Farahani M.H.D.A., Borghei S.M., Vatanpour V., Recovery of cooling tower blowdown water for reuse: Theinvestigation of different types of pretreatment prior nanofiltrationand reverse osmosis, Journal of Water Process Engineering 10 (2016) 188–199.
Feng X., Chu K., Cost optimization of industrial wastewater reuse systems, Proc. Process Safety and Environmental Protection 82 (2004) 249-255.
Gonzalez C.F., Taber W.A., Zeitoun M., Biodegradation of ethylene glycol by a salt-requiring bacterium, Applied microbiology, 24 (1972) 911-919.
Hajati S., Ghaedi M., Yaghoubi S., Local, cheep and nontoxic activated carbon as efficient adsorbent for the simultaneous removal of cadmium ions and malachite green: Optimization by surface response methodology, Journal of Industrial and Engineering Chemistry 21 (2015) 760-767.
Haines J., Alexander M., Microbial degradation of polyethylene glycols, Journal of Applied Microbiology 29 (1975) 621-625.
Hameed B., Tan I., Ahmad A., Preparation of oil palm empty fruit bunch-based activated carbon for removal of 2, 4, 6-trichlorophenol: Optimization using response surface methodology, Journal of Hazardous Materials 164 (2009) 1316-1324.
Huang Y.-L., Li Q.-B., Deng X., Lu Y.-H., Liao X.-K., Hong M.-Y., Wang Y., Aerobic and anaerobic biodegradation of polyethylene glycols using sludge microbes, Process Biochemistry 40 (2005) 207-211.
Jaria G., Calisto V., Silva C.P., Gil M.V., Otero M., Esteves V.I., Obtaining granular activated carbon from papermill sludge– A challenge for application in the removal of pharmaceuticals from wastewater, Science of the Total Environment 653 (2019) 393–400.
Mason R.L., Gunst R.F., Hess J.L., Statistical design and analysis of experiments: with applications to engineering and science, John Wiley & Sons, 2003.
McGahey C., Bouwer E., Biodegradation of ethylene glycol in simulated subsurface environments, Water Science & Technology 26 (1992) 41-49.
McQuillan R.V., Stevens G.W., Mumford K.A., The electrochemical regeneration of granular activated carbons: A review, Journal of Hazardous Materials 355 (2018) 34–49.
McVicker L., Duffy D., Stout V., Microbial growth in a steady-state model of ethylene glycol-contaminated soil, Current Microbiology 36 (1998) 136-147.
Meyer J.L., Sale M.J., Mulholland P.J., LeRoy Poff N., Impacts of climate change on aquatic ecosystem functioning and health, JAWRA Journal of the American Water Resources Association 35 (1999) 1373-1386.
Mohsen M.S., Jaber J.O., Potential of industrial wastewater reuse, Desalination 152 (2003) 281-289.
Pereira L.S., Oweis T., Zairi A., Irrigation management under water scarcity, Agricultural Water Management 57 (2002) 175-206.
Petrinic I., Korenak J., Povodnik D., Hélix-Nielsen C., A feasibility study of ultrafiltration/reverse osmosis (UF/RO)-based wastewater treatment and reuse in the metal finishing industry, Journal of Cleaner Production 101(2015) 292-300.
Rebhun M., Engel G., Reuse of wastewater for industrial cooling systems, Journal of the Water Pollution Control Federation 60 (1988) 237-241.
Revitt D., Worrall P., Low temperature biodegradation of airport de-icing fluids, Water Science & Technology 48 (2003) 103-111.
Sahu J., Acharya J., Meikap B., Response surface modeling and optimization of chromium (VI) removal from aqueous solution using Tamarind wood activated carbon in batch process, Journal of Hazardous Materials 172 (2009) 818-825.
Salehi E., Madaeni S., Rajabi L., Vatanpour V., Derakhshan A., Zinadini S., Ghorabi S., Monfared H.A., Novel chitosan/poly (vinyl) alcohol thin adsorptive membranes modified with amino functionalized multi-walled carbon nanotubes for Cu (II) removal from water: preparation, characterization, adsorption kinetics and thermodynamics, Separation and Purification Technology 89 (2012) 309-319.
Sowers J., Vengosh A., Weinthal E., Climate change, water resources, and the politics of adaptation in the Middle East and North Africa, Climatic Change 104 (2011) 599-627.
Staples C.A., Williams J.B., Craig G.R., Roberts K.M., Fate, effects and potential environmental risks of ethylene glycol: a review, Chemosphere 43 (2001) 377-383.
Straß A., Schink B., Fermentation of polyethylene glycol via acetaldehyde in Pelobacter venetianus, Applied Microbiology and Biotechnology 25 (1986) 37-42.
Vatanpour V., Salehi E., Sahebjamee N., Ashrafi M., Novel chitosan/polyvinyl alcohol thin membrane adsorbents modified with detonation nanodiamonds: Preparation, characterization, and adsorption performance, Arabian Journal of Chemistry (2018).
Vatanpour V., Sheydaei M., Esmaeili M., Box-Behnken design as a systematic approach to inspect correlation between synthesis conditions and desalination performance of TFC RO membranes, Desalination 420 (2017) 1–11.
Wongkaew K., Wannachod T., Mohdee V., Pancharoen U., Arpornwichanop A., Lothongkum A.W., Mass transfer resistance and response surface methodolog y for separation of platinum(IV) across hollow fiber supported liquid membrane, Journal of Industrial and Engineering Chemistry 42 (2016) 23–35.
Wu D., Martin J., Du J., Zhang Y., Lawless D., Feng X., Thin film composite membranes comprising of polyamide and polydopamine
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Jalili et al./ J. App. Res. Wat. Wast. 10(2018) 421-430
Please cite this article as: B. Jalili, S.M. Borghei, V. Vatanpour, C. Sarkizi, Optimization of adsorption removal of ethylene glycol from wastewater
using granular activated carbon by response surface methodology, Journal of Applied Research in Water and Wastewater, 5 (2), 2018, 421-430.
for dehydration of ethylene glycol by pervaporation, Journal of Membrane Science 493 (2015) 622-635.
Yang Y., Wang W., Wang F., Liu Y., Chai D., Lei Z., Partially oxidized NiFe alloy: An effective promoter to enhance Pd electrocatalytic performance for ethylene glycol oxidation, International Journal of Hydrogen Energy 40 (2015) 12262-12267.
Zgoła-Grześkowiak A., Grześkowiak T., Zembrzuska J., Łukaszewski Z., Comparison of biodegradation of poly (ethylene glycol)s and poly (propylene glycol)s, Chemosphere 64 (2006) 803-809.