Document Type : Research Paper

Authors

1 School of Civil Engineering, Universiti Sains Malaysia, Nibong Tebal, Pinang, Malaysia

2 Civil Engineering Department, Universiti Teknologi PETRONAS, Perak, Malaysia

3 Faculty of biological sciences, Kharazmi University, Tehran, Iran

Abstract

Electrochemical oxidation process has been shown to be a favourable choice for Chemical oxygen demand (COD) and color removals from various types of wastewaters. The technique was employed for mineralization of semi-aerobic landfill leachate. Leachate sampling were carried out from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. The main objective was to determine the effectiveness of electrochemical oxidation in leachate treatment using aluminum electrodes which are relatively nontoxic and cost-effective. The influence of pH, reaction time, current density, electrolyte concentration, agitation rate and dilution on COD and color removals was investigated. The highest COD and color removal were obtained as 57.1% and 72.0% respectively at pH 8, current density 60 mA/cm2, electrolyte concentration 2000 mg/L, agitation rate 400 rpm, dilution 50% and reaction time 4 h. The energy consumption was determined as 128 kWh/m3 for this type of landfill leachate. The study shows that electrochemical oxidation can be used as a step of shared treatment.

Keywords

APHA Standard Methods for the Examination of water and Wastewater. 23rd ed. American Public Health Association, Washington DC, pp. 1-733 (2017).
Arevalo E., Calmano W., Studies on the electrochemical treatment of wastewater contaminated with organotin compounds, Journal of Hazardous Materials 146 (2007) 540-545.
Bashir M.J.K., Isa M.H., Kutty S.R.M., Awang Z.B., Aziz H.A., Mohajeri S. and Farooqi I.H., Landfill leachate treatment by electrochemical oxidation, Waste Management 29 (2009) 2534-2541.
Bayramoglu M., Kobya M., Can O.T., Sozbir M., Operating cost analysis of electrocoagulation of textile dye wastewater, Separation and Purification Technology 37 (2004)117-125.
Bensalah N., Quiroz Alfarob M.A., Martínez-Huitle C.A., Electrochemical treatment of synthetic wastewaters containing Alphazurine A dye, Chemical Engineering Journal 149 (2009) 348-352.
Boye B., Dieng M.M., Brillas E., Anodic oxidation, electro-Fenton and photoelectro-Fenton treatments of 2, 4, 5-trichlorophenoxyacetic acid, Journal of Electroanalytical Chemistry 557 (2003) 135-146.
Chen G., Electrochemical technologies in wastewater treatment, Separation and Purification Technology 38 (2004) 11-41.
Chiang L.C., Chang J.E., Electrochemical oxidation combined with physical-chemical pretreatment processes for the treatment of refractory landfill leachate, Environmental Engineering Science 18 (2001) 369-379.
Deng Y., Englehardt J.D., Electrochemical oxidation for landfill leachate treatment, Waste Management 27 (2007) 380-388.
Deng Y., Englehardt J.D., Electrochemical oxidation for landfill leachate treatment, Waste Management 27 (2007) 380-388.
El-Ashtoukhya E.S.Z., Amina N.K., Abdelwahab O., Treatment of paper mill effluents in a batch-stirred electrochemical tank reactor, Chemical Engineering Journal 146 (2009) 205-210.
Fan Y., Ai Z., Zhang L., Design of an electro-Fenton system with a novel sandwich film cathode for wastewater treatment, Journal of Hazardous Materials 176 (2010) 678-684.
Feki F., Aloui F., Feki M., Sayadi S., Electrochemical oxidation post-treatment of landfill leachates treated with membrane bioreactor, Chemosphere 75 (2009) 256-260.
Fernandes, A., Pacheco, M. J., Ciríaco, L., & Lopes, A., Review on the electrochemical processes for the treatment of sanitary landfill leachates: Present and future, Applied Catalysis B: Environmental 176 (2015) 183-200.
Fernandes A., Santos D., Pacheco M.J., Ciríaco L., Lopes A., Electrochemical oxidation of humic acid and sanitary landfill leachate: Influence of anode material, chloride concentration and current density. Science of The Total Environment 541(2016) 282-291.
Gotsi M., Kalogerakis N., Psillakis E., Samaras P., Mantzavinos D., Electrochemical oxidation of olive oil mill wastewaters, Water Research 39 (2005) 4177-4187.
Hermosilla D., Cortijo M., Huang C.P., Optimizing the treatment of landfill leachate by conventional Fenton and photo-Fenton processes, Science of the Total Environment 407 (2009) 3473-3481.
Hmani E., Chaabane Elaoud S., Samet Y., Abdelhédi R., Electrochemical degradation of waters containing O-Toluidine on PbO2 and BDD anodes, Journal of Hazardous Materials 170 (2009) 928-933.
Ilhan F., Kurt U., Apaydin O., Gonullu M.T., Treatment of leachate by electrocoagulation using aluminum and iron electrodes, Journal of Hazardous Materials 154 (2008) 381-389.
Iniesta J., Gonzalez-Garcia J., Exposito E., Montiel V., Aldaz A., Influence of chloride ion on electrochemical degradation of phenol in alkaline medium using bismuth doped and pure PbO2 anodes, Water Research 35 (2001) 3291-3300.
Körbahti B.K., Aktaş N., Tanyolaç A., Optimization of electrochemical treatment of industrial paint wastewater with response surface methodology, Journal of Hazardous Materials 148 (2007) 83-90.
Krishna B.M., Murthy U.N., Manoj Kumar B., Lokesh K.S., Electrochemical pretreatment of distillery wastewater using aluminum electrode, Journal of Applied Electrochemistry 40 (2010) 663-673.
Li M., Wang M., Jiao Z.K., Chen Z.Y., Study on electrolytic oxidation for landfill leachate treatment, China Water and Wastewater 17 (2001) 14-17.
Mohajeri S., Hamidi A.A., Isa M.H., Zahed M.A., Landfill Leachate Treatment through electro-Fenton oxidation, Pollution, 5 (2019) 199-209.
Mohajeri S., Aziz H.A., Isa M.H., Bashir M.J.K., Mohajeri L., Adlan M.N., Influence of Fenton reagent oxidation on mineralization and decolorization of municipal landfill leachate, Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering 45 (2010b) 692-698.
Mohajeri S., Aziz H.A., Isa M.H., Zahed M.A., Adlan M.N., Statistical optimization of process parameters for landfill leachate treatment using electro-Fenton technique, Journal of Hazardous Materials 176 (2010c) 749-758.
Mohajeri S., Aziz H.A., Isa M.H., Zahed M.A., Bashir M.J.K., Adlan M.N., Application of the central composite design for condition optimization for semi aerobic landfill leachate treatment using electrochemical oxidation, Water Science and Technology 61 (2010a) 1257-1266.
Montanaroa D., Petrucci E., Electrochemical treatment of Remazol Brilliant Blue on a boron-doped diamond electrode, Chemical Engineering Journal 153 (2009) 138-144.
Moraes P.B., Bertazzoli R., Electrodegradation of landfill leachate in a flow electrochemical reactor, Chemosphere 58 (2005) 41-46.
Moreira F.C., Soler J., Fonseca A., Saraiva I., Boaventura R.A., Brillas E., Vilar V.J., Incorporation of electrochemical advanced oxidation processes in a multistage treatment system for sanitary landfill leachate, Water Research 81 (2015) 375-87.
Moreira F.C., Soler J., Fonseca, A., Saraiva, I., Boaventura R. A., Brillas E., Vilar V.J., Electrochemical advanced oxidation processes for sanitary landfill leachate remediation: Evaluation of operational variables, Applied Catalysis B: Environmental 182 (2016) 161-171.
Oturan N., Van Hullebusch E.D., Zhang H., Mazeas L., Budzinski H., Le Menach K., Oturan M.A., Occurrence and removal of organic micropollutants in landfill leachates treated by electrochemical advanced oxidation processes, Environmental Science & Technology 49 (2015) 12187-12196.
Panizza M., Cerisola G., Electrochemical degradation of gallic acid on a BDD anode, Chemosphere 77 (2009) 1060-1064.
Rivas F.J., Beltrán F., Carvalho F., Gimeno O., Frades J., Study of Different Integrated Physical−Chemical+Adsorption Processes for Landfill Leachate Remediation, Industrial & Engineering Chemistry Research 44 (2005) 2871-2878.
Shao L., He P., Xue J., Li G., Electrolytic degradation of biorefractory organics and ammonia in leachate from bioreactor landfill, Water Science and Technology 53 (2006) 143-150.
Szpyrkowicz L., Kaul S.N., Neti R.N., Satyanarayan S., Influence on the anode material on electrochemical oxidation for the treatment of tannery wastewater, Water Research 39 (2005) 1601-1613.
Szpyrkowicz L., Kelsall G., Kaul S.N., De Faveri M., Satyanarayan S., Performance of electrochemical reactor for treatment of tannery wastewaters, Chemical Engineering Science 56 (2001) 1579-1586.
Un U.T., Altay U., Koparal A.S., Ogutveren U.B., Complete treatment of olive mill wastewaters by electrooxidation, Chemical Engineering Journal 139 (2008) 445-452.
Vlyssides A.G., Karlis P.K., Mahnken G., Influence of various parameters on the electrochemical treatment of landfill leachates, Journal of Applied Electrochemistry 33 (2003) 155-159.
Wang Y., Gong B., Lin Z., Wang J., Zhang J., Zhou J., Robustness and microbial consortia succession of simultaneous partial nitrification, ANAMMOX and denitrification (SNAD) process for mature landfill leachate treatment under low temperature, Biochemical Engineering Journal 10 (2018) 1-15.
Yi F., Chen S., Yuan C., Effect of activated carbon fiber anode structure and electrolysis conditions on electrochemical degradation of dye wastewater, Journal of Hazardous Materials 157 (2008) 79-87.
Yusoff M.S., Aziz H.A., Zamri M.F.M.A., Abdullah A.Z., Basri N.E.A., Floc behavior and removal mechanisms of cross-linked Durio zibethinus seed starch as a natural flocculant for landfill leachate coagulation-flocculation treatment, Waste Management 74 (2018) 362-372.