Zakie Rostami; Masoud Rahimi; Neda Azimi
Abstract
In this study, Ni+2 removal from aqueous solution was investigated by concurrent usage of Fe3O4 nanoparticles and a high frequency ultrasound (1.7 MHz). In addition to Ni+2 removal, presence of the high frequency ultrasound led to being cooled photovoltaic (PV) module. Studied variables were pH and adsorbent ...
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In this study, Ni+2 removal from aqueous solution was investigated by concurrent usage of Fe3O4 nanoparticles and a high frequency ultrasound (1.7 MHz). In addition to Ni+2 removal, presence of the high frequency ultrasound led to being cooled photovoltaic (PV) module. Studied variables were pH and adsorbent dose (AD). Results indicated that the Ni+2 removal efficiency increased with an increase in the pH ranging from 2 to 9. Furthermore, the Ni+2 removal efficiency boosted by an increase in the AD. However, no significant enhancement in Ni+2 removal efficiency was observed at the AD above 9 g. Generally, the maximum Ni+2 removal efficiency was about 79 % for contact time of 50 min at pH=9 and AD=9 g in the presence of ultrasound. At the efficient condition (pH=9, AD=9 g and contact time=50 min), using ultrasound showed 16-20 % enhancement in Ni+2 removal efficiency compared to no ultrasound usage. From heat transfer view, it was observed that propagation of 1.7 MHz ultrasound into nanofluid significantly has cooled the photovoltaic (PV) module. Moreover, an increase in concentration of nanofluid (AD) showed a positive effect on reduction of heat from the PV module surface and maximum generated power. Obtained data demonstrated that agitating nanofluid by 1.7 MHz ultrasound decreased temperature of the PV module up to 15.5 % compared to no cooling system.
Tahereh Mansouri Jalilian; Neda Azimi; Shahin Ahmadi
Abstract
The effect of ultrasound on cobalt adsorption from aqueous solution onto Fe3O4/Bentonite nanocomposite is investigated. Two layouts of using shaker and sono-separator equipped with ultrasound are considered. The effect of pH on Co(II) ions removal is investigated. Co(II) removal rate increased with increasing ...
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The effect of ultrasound on cobalt adsorption from aqueous solution onto Fe3O4/Bentonite nanocomposite is investigated. Two layouts of using shaker and sono-separator equipped with ultrasound are considered. The effect of pH on Co(II) ions removal is investigated. Co(II) removal rate increased with increasing pH from 2 to 10, and it reduced after pH=10. For the shaker, the contact time (t) of 50 min is selected as the most effective case. However, for sono-separator the maximum value of Co(II) removal rate is 78% at t=10 min, and it decreased after 10 min. The effect of the adsorbent mass (AM) is investigated and Co(II) removal increased by increasing the specific surface area of the adsorbent. The highest Co(II) removal rates are 83.3% and 86% for the shaker and the sono-separator, respectively. No significant increase for Co(II) removal is observed for increasing AM more than 3 g. The effect of the transducer locations and initial concentration of Co(II) ions (C0) at pH=10 and AM =3 g are investigated. The results showed that the activation of all transducers had the best performance. Initially, with increasing C0 from 0.05 to 0.1 g/L, Co(II) removal rate increased from 84% to 86%, respectively, but with increasing C0 from 0.1 to 0.15 and 0.2 g/L, cobalt removal has been decreased. Finally, the experimental data are adopted with Langmuir and Freundlich isotherms. The comparison of these models showed that both models are well suited to experimental data and data compatibility with the Langmuir model is greater.
Mohammad Eisapour Chanani; Nader Bahramifar; Habibollah Younesi
Volume 2, Issue 2 , December 2015, , Pages 176-182
Abstract
The main objective of this study was to synthesize an environmentally friendly nano-structural adsorbent. These nano magnetic particles can be applied to remove heavy metal ions from industrial wastewater because the surface of the particles is covered with SiO2, and the SiO2 is inactive and can adsorb ...
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The main objective of this study was to synthesize an environmentally friendly nano-structural adsorbent. These nano magnetic particles can be applied to remove heavy metal ions from industrial wastewater because the surface of the particles is covered with SiO2, and the SiO2 is inactive and can adsorb heavy metal ions. Tests were then conducted to study the adsorption of Cu(II) ions onto Fe3O4@SiO2 from an aqueous solution for the effect of contact time, adsorbent dose, solution pH and concentration of metal ions in batch systems. The equilibrium data were analyzed using the Langmuir and Freundlich isotherm by nonlinear regression analysis and found that the adsorption isotherm data will better fit by Langmuir model. The maximum adsorption capacities of Cu (II) were 47 mg/g. Fe3O4@SiO2 was regenerated and found to be suitable for reuse in successive adsorption-desorption cycles 5 times without significant loss of adsorption capacity.