Golshan Moradi; Sirus Zinadini; Masoud Rahimi
Abstract
Fumarate-alumoxane nanoparticles (Fum-ANPs) incorporated PES nanofiltration membrane was fabricated via phase inversion to achieve favorable performance as the enhancement in the dye removal and antifouling capacity. FTIR spectra of the Fum-ANPs revealed that the carboxylate and hydroxyl functional groups ...
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Fumarate-alumoxane nanoparticles (Fum-ANPs) incorporated PES nanofiltration membrane was fabricated via phase inversion to achieve favorable performance as the enhancement in the dye removal and antifouling capacity. FTIR spectra of the Fum-ANPs revealed that the carboxylate and hydroxyl functional groups were created on the surface of Fum-ANPs. The strong affinity of Fum-ANPs functional groups with water molecules made the membrane surface more hydrophilic. Hence, the modified membrane sample had a higher pure water flux than the bare one. Zeta potential data showed that the Fum-ANPs blended PES membrane was negatively charged at a pH value of 6, which is favorable for negatively charged solute rejection. The antifouling behavior of the membranes was analyzed using powder milk solution (8 g/L) in a dead-end filtration system. The obtained results demonstrated that the introduction of Fum-ANPs in the membrane matrix ameliorated the antifouling behavior of the resulting membrane. To further study the performance of the Fum-ANPs incorporated PES membrane, removal of Direct red 16 dye was tested. The removal efficiency of Direct red 16 with the Fum-ANPs blended PES membrane was 99% while it was 88.2% for the bare membrane sample.
Golshan Moradi; Sirus Zinadini; Masoud Rahimi
Abstract
The research on membrane-based filtration technology for water treatment has expanded in recent years. Membrane fouling is a major challenge that decreases the permeability and decreases the lifetime and selectivity of the membrane. Recently, it was found that fouling mitigation and better control of ...
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The research on membrane-based filtration technology for water treatment has expanded in recent years. Membrane fouling is a major challenge that decreases the permeability and decreases the lifetime and selectivity of the membrane. Recently, it was found that fouling mitigation and better control of membrane fouling can be attained under the application of the electric field. This paper provides an overview of the application of the electric field to the filtration process and its antifouling mechanism. Utilization of conductive polymeric membranes and application of electric field in membrane bioreactors are reviewed as well. The presented review demonstrates that the introduction of negative charge into the membrane surface via preparing conductive membranes or applying an external electric field onto the membrane surface suggests several advantages. These are fouling alleviation, better control of membrane fouling, an increase of membrane resistance to cake deposition on the membrane surface, and superior possible applications such as better salt rejection and antibacterial activity.
Golshan Moradi; Farzad Dabirian; Laleh Rajabi; Ali Ashraf Derakhshan
Volume 2, Issue 2 , December 2015, , Pages 170-175
Abstract
Novel electrospun polyacrylonitrile (PAN) nanofiber mats and PAN fabric were chemically modified by dissolved anhydrous stannous chloride diethyl ether saturated with hydrogen chloride to contain aldehyde groups on their surfaces, which are suitable for ammonium adsorption due to their high adsorption ...
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Novel electrospun polyacrylonitrile (PAN) nanofiber mats and PAN fabric were chemically modified by dissolved anhydrous stannous chloride diethyl ether saturated with hydrogen chloride to contain aldehyde groups on their surfaces, which are suitable for ammonium adsorption due to their high adsorption affinity for NH4+ ion. Scanning electron microscopy (SEM), and Fourier-transform infrared spectra (FT-IR) were employed to characterize the prepared adsorbents. FT-IR spectra of these adsorbents confirmed that aldehyde groups are successfully formed on the surface of these chemically modified adsorbents. The aldehydic electrospun PAN nanofiber mats and aldehydic PAN fabric were assessed for their chelating property with NH4+ ion from aqueous solution. The effects of contact time on the amounts of ammonium adsorbed into the prepared adsorbents were also studied. Results revealed that ammonium removal increased by increasing contact time which finally reached equilibrium at about 3.5 h and 4 h for aldehydic electrospun PAN nanofiber mats and aldehydic PAN fabric, respectively. The adsorption performance of these prepared adsorbents for ammonium adsorption with initial ammonium concentration of 300 ppm via isotherm studies was investigated. The maximum ammonium removal efficiency (% R) was 48.33 and 70 for aldehydic electrospun PAN nanofiber mats and PAN fabric, respectively. Results indicated that the adsorption of ammonium by both prepared adsorbents followed Langmuir isotherm.
